It's pretty simple using Json.NET:
dynamic stuff = JsonConvert.DeserializeObject("{ 'Name': 'Jon Smith', 'Address': { 'City': 'New York', 'State': 'NY' }, 'Age': 42 }");
string name = stuff.Name;
string address = stuff.Address.City;
Also using Newtonsoft.Json.Linq:
dynamic stuff = JObject.Parse("{ 'Name': 'Jon Smith', 'Address': { 'City': 'New York', 'State': 'NY' }, 'Age': 42 }");
string name = stuff.Name;
string address = stuff.Address.City;